Hi,
I'd say the Windows native Wifi library seems like a starting point. I've never used it in LV but it works in other languages, so you will only need to match the data types
- https://msdn.microsoft.com/en-us/library/windows/desktop/ms706749(v=vs.85).aspx
wlanapi.dll is in System32 (or SysWOW64).
Other ways could be reusing high-level open-source library that pretty much do all the job. ManagedWifi is quite famous for that:
- https://managedwifi.codeplex.com/
--Eric