Basically your Windows desktop is simply an application that is started up by Windows after the user logged in (or it logs in automatically). You can change the registry entry for this to any program you like, including a LabVIEW app. Needs some careful planning ahead, because once you do that, you mostly only can do things in Windows that your application provides an interface for. So if you don't plan some way to startup for instance the file manager, you might have locked out yourself for that account pretty effectively.
One exception is Ctrl-Alt-Del which still works, but with some Windows API magic, this is quite easily remedied too. A computer that is tied down like this is pretty hard to get into in other ways than your Shell replacement app, but again watch out, this applies for you too, not just the operator noob.