I have a feeling that what you are trying to do is more advanced than what your experience can handle. However, this is how we all learn right?
An XControl won't help you. An XControl is just a nice package. You still have to figure out how to do what you want. Once you figure that out, you can then create an XControl out of it if you want, but not necessary.
I could probably implement what you want in pure LabVIEW using 2 picture controls and some other tricks, so it's definitely doable. But it's not something you can do in 5 minutes.
I suggest you study up on picture controls.
Another consideration is that you might want to change your design. You can probably use an array of picture controls which allows you to scroll through the images. Then when you hover over the one image you can overlay another array of images slightly shifted to the right.
Many creative ways to do this but not easy.