The Bitmap constructor is part of .net, not the zxing lib; look for System.Drawing.Bitmap
If your webcam exports an image, you would have to convert that to a bitmap or look through the zxing API for a method that accepts an image.
I played around with rotating my 1D barcodes and found that if you cannot draw a horizontal or vertical line that passes through all of the elements of the barcode, you will fail to decode. 2D QR codes worked without a problem.
The decode method returns a Result object; use the properties to retrieve the result points and metadata. You might need to iterate over the metadata object to get the key/value pairs.
I've attached the VI with the all of the .NET closes as pointed out in the thread. I still work in LV 8.6 and that is limited to .NET 2.0 so that's what I've posted here.
Place it in the same folder as the zxing .net 2.0 DLL and it should 'just work'.
zxing.net Read Barcode.vi