Daisy-chained / multi-dropped RS485 with a master-slave protocol? If you need an example of how that can be done in LabVIEW you can look at this one which is based on one of the industry-standard protocols for such communication - Modbus :
What is your topology? Is it a single RS485 link per slave, or are they on the same bus? If they are on the same bus, you will have to think of the communication protocol, is it token based, is it CSMA/CD? That is up to you, as the designer.